Hybrid porous tin(IV) phosphonate: an efficient catalyst for adipic acid synthesis and a very good adsorbent for CO2 uptake.
نویسندگان
چکیده
A new porous organic-inorganic hybrid tin phosphonate material has been synthesized hydrothermally, which shows a Brunauer-Emmett-Teller surface area of 723 m(2) g(-1) and it adsorbs 4.8 mmol g(-1) CO(2) at 273 K and 5 bar pressure. The material also shows remarkable catalytic activity in one-pot liquid phase oxidation of cyclohexanone to adipic acid under eco-friendly conditions.
منابع مشابه
Graphene–ZnO@SiO2 hybrid: An efficient and solid acid catalyst for synthesis of azlactones under ultrasound irradiation
The central theme of this article is how to explore a novel route to fabricate graphene– ZnO@SiO2 hybrid by a covalent process. The synthesis procedure consists of three-steps: (1) synthesis of ZnO nanoparticles, (2) ZnO nanoparticles modification by tetraethyl orthosilicate and (3-aminopropyl) triethoxysilane after introduction of amino groups on its surface, (3) the covalent attach...
متن کاملGraphene–ZnO@SiO2 hybrid: An efficient and solid acid catalyst for synthesis of azlactones under ultrasound irradiation
The central theme of this article is how to explore a novel route to fabricate graphene– ZnO@SiO2 hybrid by a covalent process. The synthesis procedure consists of three-steps: (1) synthesis of ZnO nanoparticles, (2) ZnO nanoparticles modification by tetraethyl orthosilicate and (3-aminopropyl) triethoxysilane after introduction of amino groups on its surface, (3) the covalent attach...
متن کاملSynthesis, Characterization and Application of a Novel Zirconium Phosphonate Ion-Exchanger for Removal of Ni2+, Cu2+ and Zn2+ from Aqueous Solutions
A new category of hybrid organic-inorganic zirconium phosphonate, Zr[(O3PCH2)2NC6H4CO2H].2H2O was synthesized and the applicability of the prepared sorbent as an ion-exchanger for removal of Ni2+, Cu2+ and Zn2+ from aqueous solutions was evaluated. The characterization of the synthe...
متن کاملSulfonated Porous Carbon (SPC): An efficient and recyclable solid acid catalyst for one-pot three-component synthesis of 2,3-dihydroquinazolin-4(1H)-ones under solvent-free conditions
A simple and efficient procedure has been developed for the synthesis of 2,3-dihydroquinazolin-4(1H)-ones derivatives under solvent-free conditions. This method uses the condensation of isatoic anhydride, aldehydes, and amines in the presence of a catalytic amount Sulfonated Porous Carbon (SPC). One of the important advantages of the new method is that the SPC could be recycled and reused.
متن کاملSulfonated Porous Carbon (SPC): An efficient and recyclable solid acid catalyst for one-pot three-component synthesis of 2,3-dihydroquinazolin-4(1H)-ones under solvent-free conditions
A simple and efficient procedure has been developed for the synthesis of 2,3-dihydroquinazolin-4(1H)-ones derivatives under solvent-free conditions. This method uses the condensation of isatoic anhydride, aldehydes, and amines in the presence of a catalytic amount Sulfonated Porous Carbon (SPC). One of the important advantages of the new method is that the SPC could be recycled and reused.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 48 53 شماره
صفحات -
تاریخ انتشار 2012